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You will find this discussed on the page about electronegativity. Use the BACK button on your browser to return to this page from either of these links.

Small pieces of sodium burn in air with often little more than an orange glow. Using larger amounts of sodium or burning it in oxygen gives a strong orange flame.

You get a white solid mixture of sodium oxide and sodium peroxide. Small pieces of potassium heated in air tend to just melt and turn instantly into a mixture of potassium peroxide and potassium superoxide without any flame being seen.

Larger pieces of potassium burn with a lilac flame. I have a bit of a problem with this, because over my teaching career I have heated potassium in air many times and, if memory serves correctly, it always leaves a greyish white film on the bit of porcelain you are heating it on.

I don't recall ever seeing it yellow or orange! The formula for a peroxide doesn't look too stange, because most people are familiar with the similar formula for hydrogen peroxide.

The formula for a superoxide always looks wrong! There is more about these oxides later on. Both metals catch fire in air and produce superoxides, RbO 2 and CsO 2.

The equations are the same as the equivalent potassium one. There is a bit of video from the Royal Society of Chemistry showing the two metals burning on exposure to air.

The rubidium doesn't show a clear flame colour in this video, although the caesium does show traces of blue-violet.

Both superoxides are described in most sources as being either orange or yellow. One major web source describes rubidium superoxide as being dark brown on one page and orange on another!

Lithium and to some extent sodium form simple oxides, X 2 O, which contain the common O 2- ion. Sodium and to some extent potassium form peroxides, X 2 O 2 , containing the more complicated O 2 2- ion discussed below.

Potassium, rubidium and caesium form superoxides, XO 2. The structure of the superoxide ion, O 2 - , is too difficult to discuss at this level, needing a good knowledge of molecular orbital theory to make sense of it.

The more complicated ions aren't stable in the presence of a small positive ion. Consider the peroxide ion, for example. Now imagine bringing a small positive ion close to the peroxide ion.

Electrons in the peroxide ion will be strongly attracted towards the positive ion. This is then well on the way to forming a simple oxide ion if the right-hand oxygen atom as drawn below breaks off.

We say that the positive ion polarises the negative ion. This works best if the positive ion is small and highly charged - if it has a high charge density.

Even though it only has one charge, the lithium ion at the top of the Group is so small and has such a high charge density that any peroxide ion near it falls to pieces to give an oxide and oxygen.

As you go down the Group to sodium and potassium the positive ions get bigger and they don't have so much effect on the peroxide ion.

The superoxide ions are even more easily pulled apart, and these are only stable in the presence of the big ions towards the bottom of the Group.

In the presence of sufficient oxygen, they produce the compound whose formation gives out most energy. That gives the most stable compound.

It was the only place I could track down a value for the enthalpy of formation of rubidium superoxide. If you think she is going to sleep with him anyway, i would let her know that you still think she is a bit young but if she is still sure that she wants to do this then help arm her the pill and condoms, if she's going to do it anyway then at least it will be safely, mostly down to yourself being such an open and honest mother.

Really hard one though, you have my sympathy's,it's a hard slog this teenage thing. I think im going to arm her with all the reasons against it see how she still feels after that and if shes still dead set on it arrange to go to the family planning centre with her and her bf.

I will let her know that although im not happy about it im still there for her. I think you are a fantastic mum, your dd is so lucky. I became sexually active at 14 with my bf who I had been with for 18 months.

I could not speak to my parents about such a toboo subject. As you quite rightly said she will probably do it anyway. My advise is talk as much as possible, keep the door open for her to start a disscusion anytime she wants.

If they do then your job is to make sure they get as few opportunities as poss, such as not been alone in house etc.

Hiya It's a difficult one really.. I think you should sit down and explain to her that she is too young and explain why the age of consent is there.

Perhaps even let her read some of the unplanned pregnancy stories on here? Having said that, I do think if she is going to do it then she is going to do it.

I was on the pill from aged 14 for my periods and I think it would be worth her going to the docs and going on it perhaps just incase. Also perhaps you could put some condoms in a box for her and give them to her.

Good luck with everything, you sound like a fab mum xx Hiya It's a difficult one really.. Deleted profile. Firstly, I think that the fact that your daughter is willing to discuss this with you is fantastic!

Not many 14 year olds would do that, you must have a great relationship. I can't give any advice that hasn't already been given, just express your concerns about sex at such a young age reminding her that it is illegal, as well but remember if she is intent on doing it, then she probably will.

So make sure she knows about the contraception available to her at her age. Good luck hunni xx Firstly, I think that the fact that your daughter is willing to discuss this with you is fantastic!

Good luck hunni xx. You must have a very open relationship that's fab. People are right when they say she is under the legal age of consent.

It would only take a teacher at school to find out and they would inform the police which is a whole heap of trouble nobody needs.

Thanx so much for all your help. I have arranged an evening with her tonight and my husband and son are making themself scarce.

Michelle I think you're going about it completely the right way! Yay you :- My DD is nearly 11 and I so hope our relationship is the same as yours when she's We're close now and I try to be honest but we've not reached the teens yet, it could all change and that is scary!

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